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An on-surface reaction confined within a porous molecular template
(The University of Nottingham, 2019-04-25)
On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the ...
Ullmann coupling reactions on Ag(111) and Ag(110): substrate influence on the formation of covalently coupled products and intermediate metal-organic structures
(The University of Nottingham, 2017-11-09)
On-surface reactions based on Ullmann coupling are known to proceed on coinage-metal substrates (e.g. Au, Ag,
Cu), with the chemistry of the surface strongly influencing the reaction progression. In addition, the topography ...
On-Surface Synthesis within a Porphyrin Nanoring Template
(The University of Nottingham, 2019-06-28)
On-surface synthesis provides a route for the production of 1D and 2D covalently bonded polymeric structures. Such reactions are confined to the surface of a substrate and the catalytic properties of the substrate are often ...
Structural characterisation of molecular conformation and the incorporation of adatoms in an on-surface Ullmann-type reaction
(The University of Nottingham, 2020-11-03)
The on-surface synthesis of covalently bonded materials differs from solution-phase synthesis in several respects. The transition from a three-dimensional reaction volume to quasi two-dimensional confinement, as is the ...