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      An on-surface reaction confined within a porous molecular template

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      Judd_et_al_Chem_Eur_J_Data.zip (87.86Mb)
      Publication date
      2019-04-25
      Creators
      Saywell, Alex
      Metadata
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      Description
      On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an on-surface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another.
      External URI
      • https://rdmc.nottingham.ac.uk/handle/internal/335
      DOI
      • http://doi.org/10.17639/nott.331
      Links
      • https://doi.org/10.1002/chem.201704693
      • http://doi.org/10.17639/nott.331
      Subjects
      • Heterogeneous catalysis
      • Scanning probe microscopy
      • Supramolecular chemistry
      • Surface chemistry
      • heterogeneous catalysis, supramolecular chemistry, scanning probe microscopy, surface chemistry, templated reactions
      • Physical sciences::Chemistry::Physical chemistry
      • Physical sciences::Physics::Chemical physics, Solid-state physics
      • Q Science::QD Chemistry::QD450 Physical and theoretical chemistry
      Divisions
      • University of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomy
      • University of Nottingham, UK Campus::Faculty of Science::School of Chemistry
      Deposit date
      2019-04-25
      Data type
      Scanning tunnelling microscopy images (STM)
      Contributors
      • Judd, Chris J.
      • Champness, Neil R.
      Funders
      • Other
      • Engineering & Physical Sciences Research Council
      • People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme
      Grant number
      • 623992-TOPCHEM
      • EPSRC Doctoral Training Grant
      Data collection method
      Scanning Tunelling Microscopy (STM): Omicron LT- UHV STM/AFM system + Omicron STM-1 RT-UHV system
      Resource languages
      • en
      Publisher
      The University of Nottingham

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