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dc.contributor.authorJudd, Chris J.
dc.contributor.authorSaywell, Alex
dc.contributor.otherNizovtsev, Anton S.
dc.contributor.otherPlougmann, Rikke
dc.contributor.otherKondratuk, Dmitry V.
dc.contributor.otherAnderson, Harry L.
dc.contributor.otherBesley, Elena
dc.date.accessioned2020-10-14T07:43:35Z
dc.date.available2020-10-14T07:43:35Z
dc.date.issued2020-10-14
dc.identifier.urihttps://rdmc.nottingham.ac.uk/handle/internal/8611
dc.description.abstractThe electronic structure of a molecular quantum ring (stacks of 40-unit cyclic porphyrin polymers) is characterised via scanning tunnelling microscopy and scanning tunnelling spectroscopy. Our measurements access the energetic and spatial distribution of the electronic states and, utilising a combination of density functional theory and tight binding calculations, we interpret the experimentally obtained electronic structure in terms of coherent quantum states confined around the circumference of the π-conjugated macrocycle. These findings demonstrate that large (53 nm circumference) cyclic porphyrin polymers have the potential to act as molecular quantum rings.en_UK
dc.language.isoenen_UK
dc.publisherThe University of Nottinghamen_UK
dc.rightsCC-BY*
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subject.lcshElectronic structureen_UK
dc.subject.lcshMicroscopyen_UK
dc.subject.lcshMolecular structureen_UK
dc.subject.lcshTunneling spectroscopyen_UK
dc.subject.lcshNanostructured materialsen_UK
dc.subject.lcshDensity functionalsen_UK
dc.subject.lcshPolymersen_UK
dc.titleMolecular quantum ring formed from a pi-conjugated macrocycleen_UK
dc.identifier.doihttp://doi.org/10.17639/nott.7077
dc.subject.freeOn-surface synthesis, scanning tunnelling microscopy (STM), Molecular quantum rings, density functional theory, nanorings, Polymers; Surface chemistryen_UK
dc.subject.jacsPhysical sciences::Chemistry::Physical chemistryen_UK
dc.subject.jacsPhysical sciences::Physics::Chemical physics, Solid-state physicsen_UK
dc.subject.lcQ Science::QD Chemistry::QD450 Physical and theoretical chemistryen_UK
dc.date.collection04/08/2017 - 29/08/2017en_UK
uon.divisionUniversity of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomyen_UK
uon.divisionUniversity of Nottingham, UK Campus::Faculty of Science::School of Chemistryen_UK
uon.funder.controlledEngineering & Physical Sciences Research Councilen_UK
uon.funder.controlledEngineering & Physical Sciences Research Councilen_UK
uon.datatypeScanning tunnelling microscopy images (STM)en_UK
uon.funder.freeLeverhulme Trusten_UK
uon.funder.freeRoyal Society Wolfson Fellowshipen_UK
uon.funder.freePeople Programme (Marie Curie Actions) of the European Union’s Seventh Framework Programmeen_UK
uon.funder.freeRoyal Society University Research Fellowshipen_UK
uon.funder.freeERCen_UK
uon.grantRPG-2016-104en_UK
uon.grant623992-TOPCHEMen_UK
uon.grantEP/P020232/1en_UK
uon.grantEP/J007161/1en_UK
uon.grant320969en_UK
uon.collectionmethodScanning Tunelling Microscopy (STM): Omicron LT STM/AFM system, Omicron STM-1en_UK
uon.preservation.rarelyaccessedtrue


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