IMPORTANT NOTICE: Researchers depositing data may encounter a "connection reset" error after a few moments, if uploading files greater than 2GB in size. This issue is currently being looked into.

Show simple item record

dc.contributor.authorLam, Hon Wai
dc.contributor.otherGroves, Alistair
dc.contributor.otherMartínez, Jose
dc.contributor.otherSmith, Joshua
dc.date.accessioned2018-07-23T09:23:57Z
dc.date.available2018-07-23T09:23:57Z
dc.date.issued2018-07-23
dc.identifier.urihttps://rdmc.nottingham.ac.uk/handle/internal/369
dc.description.abstractRaw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking". Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from hydrorhodation of 1,3-dienes undergo chain walking toward esters, amides, or (hetero)arenes over distances of up to eight ethylene units. The final, more highly conjugated allylrhodium species undergo nucleophilic allylation with aldehydes and an imine to give Z-homoallylic alcohols and amines, respectively.en_UK
dc.language.isoenen_UK
dc.publisherThe University of Nottinghamen_UK
dc.subject.lcshHomogeneous catalysisen_UK
dc.subject.lcshIsomerizationen_UK
dc.subject.lcshRhodiumen_UK
dc.titleRaw data for new compounds described in the paper: "Remote Nucleophilic Allylation by Allylrhodium Chain Walking"en_UK
dc.identifier.doihttp://doi.org/10.17639/nott.365
dc.subject.freeallylation; chain walking; homogeneous catalysis; isomerization; rhodiumen_UK
dc.subject.jacsPhysical sciences::Chemistry::Physical chemistryen_UK
dc.subject.lcQ Science::QD Chemistry::QD450 Physical and theoretical chemistryen_UK
uon.divisionUniversity of Nottingham, UK Campus::Faculty of Science::School of Chemistryen_UK
uon.funder.controlledEngineering & Physical Sciences Research Councilen_UK
uon.funder.controlledOtheren_UK
uon.datatypeIR, NMR, and mass spectrometry dataen_UK
uon.funder.freeThe Basque Country Governmenten_UK
uon.funder.freeLeverhulme Trusten_UK
uon.funder.freeGlaxoSmithKlineen_UK
uon.grantEP/M50810X/1 and EP/K504348/1 and RPG-2016-341en_UK
uon.collectionmethodUsing IR, NMR, and mass spectrometersen_UK
uon.preservation.rarelyaccessedtrue
dc.relation.doi10.1002/chem.201803574en_UK


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record