An on-surface reaction confined within a porous molecular template
dc.contributor.author | Saywell, Alex | |
dc.contributor.other | Judd, Chris J. | |
dc.contributor.other | Champness, Neil R. | |
dc.date.accessioned | 2019-04-25T12:42:03Z | |
dc.date.available | 2019-04-25T12:42:03Z | |
dc.date.issued | 2019-04-25 | |
dc.identifier.uri | https://rdmc.nottingham.ac.uk/handle/internal/335 | |
dc.description.abstract | On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an on-surface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another. | en_UK |
dc.language.iso | en | en_UK |
dc.publisher | The University of Nottingham | en_UK |
dc.relation.uri | https://doi.org/10.1002/chem.201704693 | en_UK |
dc.subject.lcsh | Heterogeneous catalysis | en_UK |
dc.subject.lcsh | Scanning probe microscopy | en_UK |
dc.subject.lcsh | Supramolecular chemistry | en_UK |
dc.subject.lcsh | Surface chemistry | en_UK |
dc.title | An on-surface reaction confined within a porous molecular template | en_UK |
dc.identifier.doi | http://doi.org/10.17639/nott.331 | |
dc.subject.free | heterogeneous catalysis, supramolecular chemistry, scanning probe microscopy, surface chemistry, templated reactions | en_UK |
dc.subject.jacs | Physical sciences::Chemistry::Physical chemistry | en_UK |
dc.subject.jacs | Physical sciences::Physics::Chemical physics, Solid-state physics | en_UK |
dc.subject.lc | Q Science::QD Chemistry::QD450 Physical and theoretical chemistry | en_UK |
uon.division | University of Nottingham, UK Campus::Faculty of Science::School of Physics and Astronomy | en_UK |
uon.division | University of Nottingham, UK Campus::Faculty of Science::School of Chemistry | en_UK |
uon.funder.controlled | Other | en_UK |
uon.funder.controlled | Engineering & Physical Sciences Research Council | en_UK |
uon.datatype | Scanning tunnelling microscopy images (STM) | en_UK |
uon.funder.free | People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme | en_UK |
uon.grant | 623992-TOPCHEM | en_UK |
uon.grant | EPSRC Doctoral Training Grant | en_UK |
uon.collectionmethod | Scanning Tunelling Microscopy (STM): Omicron LT- UHV STM/AFM system + Omicron STM-1 RT-UHV system | en_UK |
uon.preservation.rarelyaccessed | true |
Files in this item
This item appears in the following Collection(s)
-
Public Research Data
A collection of research data, held in this repository, that is publicly available, except where individual embargoes apply